Traveling Wave Solutions for Case Ii Diffusion in Polymers

نویسنده

  • THOMAS P. WITELSKI
چکیده

Case II diiusion of penetrant liquids in polymer lms is characterized by constant-velocity propagation of a phase interface. We review the development of viscoelastic models describing Case II diiusion and then present a phase plane analysis for traveling wave solutions. For simpliied, piecewise-constant coeecient models we give closed form analytic solutions showing the dependence on various physical parameters in both viscous and viscoelastic diiusive systems. We will also compare the results of our analysis with results from numerical simulations of more general models.

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تاریخ انتشار 1995